By Herbert August Laitinen, Walter E. Harris
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The first inflection point is usually near the 50% neutralization point, but follows it for very weak acids, precedes it for moderately strong acids, and disappears for the strongest acids. 1 M solutions) amounts to as much as 1 ppt only for very weak acids (K,< or highly dilute solutions. The second inflection point disappears for highly dilute or exceedingly weak acids. Automated techniques for end-point detection normally rely on the inflection point; significant error therefore may be incurred under certain circumstances.
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