By Amelia Pilar Rauter, Thisbe Lindhorst, Yves Queneau, M. Philippe, Jacques Auge, Valerie Molinier, Mattieu Sauthier, Yves Chapleur, Jean-Marie Beau, Qian Wan, Marie-Christine Scherrmann, Richard Daniellou, Jose Kovensky, Slawomir Jarosz, Jean-Maurice Malle
Volume forty of Carbohydrate Chemistry: Chemical and organic ways demonstrates the significance of the glycosciences for innovation and societal growth. Carbohydrates are molecules with crucial roles in biology and likewise function renewable assets for the iteration of recent chemical substances and fabrics. Honouring Professor André Lubineau’s reminiscence, this quantity resembles a unique number of contributions within the fields of eco-friendly and low-carbon chemistry, leading edge artificial technique and layout of carbohydrate architectures for medicinal and organic chemistry.
Green technique is illustrated by means of debts at the business improvement of water-promoted reactions (C-glycosylation, cycloadditions) and the layout of eco-friendly techniques and synthons in the direction of sugar-based surfactants and fabrics. The specifically demanding differences on the anomeric heart are awarded in different contributions on glycosylation methodologies utilizing iron or gold catalysis, electrochemical or enzymatic (thio)glycosylation, exo-glycal chemistry and bioengineering of carbohydrate synthases. Then, synthesis and constitution of multivalent and supramolecular oligosaccharide architectures are mentioned and relating to their actual homes and alertness power, e.g. for deepening our realizing of organic tactics, comparable to enzymatic pathways or bacterial adhesion, and layout of antibacterial, antifungal and cutting edge anticancer vaccines or drugs.
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Extra resources for Carbohydrate Chemistry: Volume 40
2011, 13, 321. 10 | Carbohydr. , 2014, 40, 1–10 Lubineau’s green synthons Jacques Auge ´ * and Nade ` ge Lubin-Germain 12/04/2014 11:51:13. 1039/9781849739986-00011 Some seminal contributions of Professor Lubineau in the field of water-promoted reactions and glycochemistry are reviewed. Notably, three types of synthons, namely a-hydroxy-g-lactones, glycosylamines and C-glycosyl compounds, can be regarded as new tools in the hands of chemists or biochemists involved in green chemistry, bioconjugate chemistry, glycochemistry or glycobiology, as evidenced by their applications in many diﬀerent fields.
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