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By Scott A. Snyder, Erick M. Carreira, Carl P. Decicco, Alois Fürstner, Guido Koch, Gary A. Molander, Ernst Schaumann

The quick velocity of evolution in domino, or cascade-based changes has revolutionized the perform of chemical synthesis for the construction of ordinary items, designed molecules, and pharmaceuticals.


"Science of Synthesis: functions of Domino variations in natural Synthesis" explores the subject completely and systematically, serving because the foundation for useful purposes and destiny study. The 2-volume set provides the state-of-the-art when it comes to layout, process, and experimental tactics, resulting in a number of occasions being finished inside of a unmarried response vessel. The content material is prepared by way of the middle form of response used to start up the development, be it a pericyclic response, a metal-mediated transformation, radical chemistry, or an acid-induced cascade between many others.


Volume 1 covers polyene/cation-pi cyclizations, metathesis, radical, and metal-mediated reactions, and non-radical skeletal rearrangements.

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Extra info for Applications of Domino Transformations in Organic Synthesis, Volume 1

Example text

1 Palladium-Mediated Domino Reactions E. A. 1 Palladium-Mediated Domino Reactions . . . . . . . . . . . . . . . . . 1 Reactions Initiating with Alkenylpalladium Intermediates . . . . . . . . . . 2 Reactions Initiating with Arylpalladium Species . . . . . . . . . . . . . . . 3 Reactions Initiating with Allylpalladium Intermediates . . . . . . . . . . . 4 Reactions Initiating with Allenylpalladium Intermediates .

2 Retro-Benzilic Acid Rearrangements . . . . . . . . . . . . . . . . . . . . 3 Favorskii Rearrangements . . . . . . . . . . . . . . . . . . . . . . . . . 1 Homo-Favorskii Rearrangements . . . . . . . . . . . . . . . . . . . . . 4 Æ-Hydroxy Ketone Rearrangements . . . . . . . . . . . . . . . . . . . . -H. -Q. Tu, and M. 2 Lewis Acid/Base Induced Reactions . . . . . . . .

6 Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Dirhodium-Catalyzed Domino Reactions X. Xu, P. Truong, and M. P. 2 Dirhodium-Catalyzed Domino Reactions . . . . . . . . . . . . . . . . . 2 Dirhodium(II)-Catalyzed Generation of Rhodium–Carbenes from Cyclopropenes and Their Subsequent Reactions . . . . . . . . . . . . . . 3 Dirhodium(II)-Catalyzed Carbene/Alkyne Metathesis . . .

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