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By W.A. E. McBryde

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Additional info for A Critical Review of Equilibrium Data for Proton and Metal Complexes of 1,10–phenanthroline, 2,2'–Bipyridyl and Related Compounds. Critical Evaluation of Equilibrium Constants in Solution: Stability Constants of Metal Complexes

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80 Medium Method Reference 50% aq. EtOH 1 48A 50% aq. Dioxane 1 61J 10% aq. 54 25 75% aq. 65 25 50% aq. 40 25 50% aq. 00 25 50% aq. 30 25 50% aq. 43 25 50% aq. 30 25 50% aq. 10 - 50% aq. 43 25 50% aq. 65 25 50% aq. 80 25 50% aq. 23 50% aq. 13 25 25% aq. MeOH 50% aq. MeOH 75% aq. 73 25 25% aq. EtOH 50% aq. EtOH 75% aq. l (Continued) Substituent Unsubstituted pKi Method Reference 25 25% aq. n-PrOH 50% aq. n-PrOH 75% aq. 58 25 25% aq. Me 2 CO 50% aq. M e 2 C 0 75% aq. 2 7 ON 25 25 25 25 25 25 25 25 25 25 Aq.

97 25 50% aq. l (Continued) Substituent Unsubstituted pKi Method Reference 25 25% aq. n-PrOH 50% aq. n-PrOH 75% aq. 58 25 25% aq. Me 2 CO 50% aq. M e 2 C 0 75% aq. 2 7 ON 25 25 25 25 25 25 25 25 25 25 Aq. 001 I 8% aq. 4% aq. 3% aq. 4% aq. 0% aq. 1% aq. 7% aq. 0% aq. 6% aq. 2 Temp. PKi Temp. 34 20 20% aq. 62 25 50% aq. 47 25 50% aq. 41 25 50% aq. 58 25 50% aq. 94 25 75% aq. 40 25 50% aq. 97 25 50% aq. 2 (Continued) pKi Temp. 23 25 50% aq. 38 25 50% aq. 59 25 50% aq. 25 25 50% aq. 98 25 50% aq. 45 25 50% aq.

91 14b 72Bg Cd(II) 25 50% EtOH, 0 . 67 4,7-Dichlorophenanthroline Fe(II) - EtOH, 0 . 1 OAc" Cu(I) 25 50% DOX, 0 . 5 16 Cu(II) 25 50% DOX, 0 . 2 11 61J 14b 72Bg 14a 72Bg 5-Bromophenani t h r o l i n e Ni(II) 25 50% EtOH, 0 . 12 Ag(I) 25 50% EtOH, 0 . 08 Zn(II) 25 50% EtOH, 0 . 69 14b 72Bg Cd(II) 25 50% EtOH, 0 . 3 Metal ion (Continued) Medium Temp. 4 Metal ion Stability Constants of Bipyridyl Metal Complexes (Mixed or Non-aqueous Solvents) Medium Temp. 8Dt 12 66B 25 Aq. 001 M in all 8% aq. 4% aq.

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